01-05-2021



How many valence electrons can Sulfur hold?

Again, consider sulfur, S, which, based on its electron configuration, has 6 valence electrons. Sulfur is located in the 16 th column of the periodic table. However, the 'A/B System' is. If a neutral sulfur atom gains two more valence electrons into its valence shell, then it will achieve a stable electron configuration identical to argon (Ar). The result is the sulfide anion. Total valence electrons given by two oxygen atoms = 6. 2 = 12 Total valence electrons given by sulfur atom = 6. 1 = 6 There are no charges in SO 2 molecule. Therefore, no addition or reduction of valence electrons due to charges.

Now sulfur has 6 unpaired electrons which means it can form 6 covalent bonds to give a total of 12 electrons around its valence shell. So in addition to being octet, sulfur can expand octet to have 10 or 12 electrons.

Can sulfur have more than 8 valence electrons?

Unlike atoms from periods one and two that only have the s and p orbitals (total of 8 valence electrons), atoms like phosphorus, sulfur, and chlorine can have more than 8 electrons because they are not restricted to the s and p orbitals and have a d orbital for additional electrons needed for bonding.

Does sulfur have 16 valence electrons?

Sulfur has 6 valence electrons located in its outermost orbit. When looking at the sulfur atom, it contains 16 total electrons.

Does sulfur have 7 valence electrons?

Explanation: Sulfur has six valence electrons. Valence electrons are the outermost electrons which, therefore, are located on the highest energy levels.

Why does boron only need 6 valence electrons?

Boron has a charge of 5. This is balanced by 5 electrons. The valence electrons may participate in bonding through sharing with other atoms, to make three bonds. Three bonds = six electrons.

Why can phosphorus make 5 bonds?

Phosphorus can have expanded octet, because it can shift it’s lone pair electrons (3s orbital electrons) to empty 3d obital during excited state and thus can form 5 bonds.

Why can an atom only have 8 valence electrons?

The octet rule refers to the tendency of atoms to prefer to have eight electrons in the valence shell. When atoms have fewer than eight electrons, they tend to react and form more stable compounds.

Why does the third shell have 8 electrons?

The electron capacity of the third shell is 8, when there are no shells above it. And that is the case for all elements in the third period. It is only when there are outer shells surrounding it that the third (or higher) shell has a higher capacity.

Why is the maximum number of valence electrons 8?

Generally, the maximum number of electrons that the outermost shell of an atom can have is 8 (eight). This is called an octet and the restriction is because the valence electrons are generally from the s and p orbitals which can have a maximum of 8 electrons.

What is the charge for sulfur?

1.17: Ions

ElementProtonsNet Charge
Potassium atom19
Potassium ion19+1
Sulfur atom16
Sulfur ion16−2

How do you find the Valency of Sulphur in SO2?

Sulphur has the atomic number of 16. Its electronic configuration is 2,8,6. The valency of S depends upon its oxidation state and with which element it reacts. For example, the valency of S in SO2 is +4 and in SO3 is +6.

Does sulfur have 3 valence electrons?

Valence electrons are the electrons in the outermost principal quantum level of an atom. Sometimes, the outermost energy level is called the valence shell. The outer energy level in this atom is n = 3. It holds six electrons, so sulfur has six valence electrons.

How many bonds can sulfur form?

Sulfur, like oxygen, frequently forms two bonds.

Does sulfur electron dot diagram have six dots?

Two negative charges means sulfur atom has gained two electrons so its electronic configuration is with 18 electrons (instead of 16). Lewis dot structure will have 4 paired dots around Sulfur atom.

Valence Electrons

As was mentioned in a previous section of this chapter, electrons are highly important, because a specific subset of electrons, called valence electrons, are solely-responsible for determining how elements bond with one another. The number of valence electrons that are present in an atom can be determined from that atom's electron configuration. Valence electrons are found in the orbitals associated with an atom's highest occupied energy level. The remaining electrons, which are called inner shell electrons, do not participate in bonding and are, therefore, not important to study.

Consider sulfur's electron configuration, which was determined in the previous section and is replicated below.

1s22s22p63s23p4

Recall that the energy levels in an electron configuration are the leading red numbers that denote the start of a new energy level/orbital combination. Sulfur has electrons in the first, second, and third energy levels, as indicated by the leading red1, 2's, and 3's, respectively. Valence electrons are those found in the highest occupiedenergy level. Therefore, in this case, only those electrons associated with an energy level/orbital combination beginning with a 3 need to be considered. Since two energy level/orbital combinations begin with a 3, both orbitals are selected for further consideration:

3s23p4

The superscripts associated with these orbitals total to 6. Therefore, sulfur has 6 valence electrons.

Example (PageIndex{1})

Determine how many of nitrogen's electrons are classified as valence electrons. Nitrogen's electron configuration, which was determined in the previous section, is shown below.

1s22s22p3

Solution

Nitrogen has electrons in the first and second energy levels, as indicated by the leading red1 and 2's, respectively. Valence electrons are those found in the highest occupiedenergy level. Therefore, in this case, only those electrons associated with an energy level/orbital combination beginning with a 2 need to be considered. Since two energy level/orbital combinations begin with a 2, both orbitals are selected for further consideration:

2s22p3

The superscripts associated with these orbitals total to 5. Therefore, nitrogen has 5 valence electrons.

Exercise (PageIndex{1})

Determine how many of the electrons in each of the following elements are classified as valence electrons. Each element's electron configuration, which was determined in the previous section, is shown below.

  1. Neon

1s22s22p6

  1. Calcium

1s22s22p63s23p64s2

Answer a
Neon has electrons in the first and second energy levels, as indicated by the leading red1 and 2's, respectively. Valence electrons are those found in the highest occupiedenergy level. Therefore, in this case, only those electrons associated with an energy level/orbital combination beginning with a 2 need to be considered. Since two energy level/orbital combinations begin with a 2, both orbitals are selected for further consideration:

2s22p6

The superscripts associated with these orbitals total to 8. Therefore, neon has 8 valence electrons.
Answer b
Calcium has electrons in the first, second, third, and fourth energy levels, as indicated by the leading red1, 2's, 3's, and 4, respectively. Valence electrons are those found in the highest occupiedenergy level. Therefore, in this case, only those electrons associated with an energy level/orbital combination beginning with a 4 need to be considered. Since only one energy level/orbital combination begins with a 4, only one orbital is selected for further consideration:

4s2

The superscript associated with this orbitalSulfur Valence Electrons is a

Sulfur Valence Electrons Number

2. Therefore, calcium has 2 valence electrons.

While an electron configuration represents all of the electrons present in an atom of an element, chemists are only truly interested in an atom's valence electrons, since, as indicated above, those are the electrons that are solely-responsible for determining how elements bond with one another. Therefore, finding a 'shortcut' for determining how many valence electrons are present in an atom would be highly convenient. Such a 'shortcut' does, indeed, exist. In a previous section of this chapter, three systems for labeling the groups, or columns, on the periodic table were presented. The second system, which is called the 'A/B System,' was indicated to provide insight into the electronic character of elements found within that group.

Again, consider sulfur, S, which, based on its electron configuration, has 6 valence electrons.

Valence Electron Configuration Chart

Sulfur is located in the 16th column of the periodic table. However, the 'A/B System' is used to label the main group elements. Group 16 is the 6th column in the main group, or 'A-Block,' columns of the periodic table and so is labeled as Group 6A. Note that sulfur's valence electron count matches its group number in the 'A/B System.' This connection applies to nearly all elements found in the main group columns of the periodic table. Helium is the only exception to this rule, as it is found in Group 8A, but only contains two total electrons. This inconsistency invalidates the 'A/B shortcut' method, and the electron configuration method must be employed to determine that both of helium's electrons are valence electrons.

Since the 'A/B System' group number corresponds to the number of valence electrons that are present in an atom, all elements found within the same column have the same number of valence electrons. Since an atom's valence electrons are solely-responsible for determining how elements bond with one another, this commonality in electronic character explains why all of the elements within the same group share similar properties.

Example (PageIndex{2})

Sulfur Valence Electrons Shell

Based on its location on the periodic table, determine how many of nitrogen's electrons are classified as valence electrons.

Solution

Sulfur Valence Electrons Octet Rule

The 'A/B System' group number indicates the number of valence electrons that are present in an atom. Nitrogen (N) is located in the 15th column of the periodic table. However, the 'A/B System' is used to label the main group elements. Group 15 is the 5th column in the main group, or 'A-Block,' columns of the periodic table and so is labeled as Group 5A. Therefore, nitrogen has 5 valence electrons. (This answer is consistent with the solution to Example (PageIndex{1}).)

Exercise (PageIndex{2})

Based on the periodic table, determine how many of the electrons in each of the following elements are classified as valence electrons.

  1. Neon
  2. Calcium
Answer a
The 'A/B System' group number indicates the number of valence electrons that are present in an atom. Neon (Ne) is located in Group 18, which is labeled as Group 8A, using the 'A/B System.' Therefore, neon has 8 valence electrons. (This answer is consistent with the solution to Exercise (PageIndex{1}text{a}).)
Answer b
Calcium (Ca) is located in Group 2, which is labeled as Group 2A in the 'A/B System.' Therefore, calcium has 2 valence electrons. (Again, this answer is consistent with the solution to Exercise (PageIndex{1}text{b}).)